{"id":554,"date":"2026-03-12T10:00:03","date_gmt":"2026-03-12T09:00:03","guid":{"rendered":"https:\/\/mxs-refractories.com\/?p=554"},"modified":"2026-03-11T15:13:22","modified_gmt":"2026-03-11T14:13:22","slug":"why-residual-quartz-should-be-1-in-silica-refractory-bricks","status":"publish","type":"post","link":"https:\/\/mxs-refractories.com\/de\/why-residual-quartz-should-be-1-in-silica-refractory-bricks\/","title":{"rendered":"Warum der Restquarz &lt; 1%  in Silika-Feuerfeststeinen betragen sollte?"},"content":{"rendered":"<div>\n<div class=\"flex h-svh w-screen flex-col\">\n<div class=\"relative z-0 flex min-h-0 w-full flex-1\">\n<div class=\"relative flex min-h-0 w-full flex-1\">\n<div class=\"@container\/main relative flex min-w-0 flex-1 flex-col -translate-y-[calc(env(safe-area-inset-bottom,0px)\/2)] pt-[calc(env(safe-area-inset-bottom,0px)\/2)]\">\n<div class=\"@w-sm\/main:[scrollbar-gutter:stable_both-edges] touch:[scrollbar-width:none] relative flex min-h-0 min-w-0 flex-1 flex-col [scrollbar-gutter:stable] not-print:overflow-x-clip not-print:overflow-y-auto scroll-pt-(--header-height) [--sticky-padding-top:var(--header-height)] has-data-[fixed-header=less-than-xl]:@w-xl\/main:scroll-pt-0 has-data-[fixed-header=less-than-xl]:@w-xl\/main:[--sticky-padding-top:0px] has-data-[fixed-header=less-than-xxl]:@w-2xl\/main:scroll-pt-0 has-data-[fixed-header=less-than-xxl]:@w-2xl\/main:[--sticky-padding-top:0px]\" data-scroll-root=\"\">\n<p>&nbsp;<\/p>\n<div id=\"thread\" class=\"group\/thread flex flex-col min-h-full\">\n<div class=\"composer-parent flex flex-1 flex-col focus-visible:outline-0\" role=\"presentation\">\n<div class=\"relative basis-auto flex-col -mb-(--composer-overlap-px) [--composer-overlap-px:28px] grow flex\">\n<div class=\"flex flex-col text-sm pb-25\" data-np-autofill-form-type=\"other\" data-np-checked=\"1\" data-np-watching=\"1\">\n<article class=\"text-token-text-primary w-full focus:outline-none [--shadow-height:45px] has-data-writing-block:pointer-events-none has-data-writing-block:-mt-(--shadow-height) has-data-writing-block:pt-(--shadow-height) [&amp;:has([data-writing-block])&gt;*]:pointer-events-auto scroll-mt-[calc(var(--header-height)+min(200px,max(70px,20svh)))]\" dir=\"auto\" tabindex=\"-1\" data-turn-id=\"request-WEB:ab09d9bb-77f2-4fdb-850d-8d2103895835-5\" data-testid=\"conversation-turn-6\" data-scroll-anchor=\"true\" data-turn=\"assistant\">\n<div class=\"text-base my-auto mx-auto pb-10 [--thread-content-margin:var(--thread-content-margin-xs,calc(var(--spacing)*4))] @w-sm\/main:[--thread-content-margin:var(--thread-content-margin-sm,calc(var(--spacing)*6))] @w-lg\/main:[--thread-content-margin:var(--thread-content-margin-lg,calc(var(--spacing)*16))] px-(--thread-content-margin)\">\n<div class=\"[--thread-content-max-width:40rem] @w-lg\/main:[--thread-content-max-width:48rem] mx-auto max-w-(--thread-content-max-width) flex-1 group\/turn-messages focus-visible:outline-hidden relative flex w-full min-w-0 flex-col agent-turn\" tabindex=\"-1\">\n<div class=\"flex max-w-full flex-col gap-4 grow\">\n<div class=\"min-h-8 text-message relative flex w-full flex-col items-end gap-2 text-start break-words whitespace-normal [.text-message+&amp;]:mt-1\" dir=\"auto\" data-message-author-role=\"assistant\" data-message-id=\"b4f30589-5710-4160-a263-f042b247a10d\" data-message-model-slug=\"gpt-5-3\">\n<div class=\"flex w-full flex-col gap-1 empty:hidden\">\n<div class=\"markdown prose dark:prose-invert w-full wrap-break-word light markdown-new-styling\">\n<p data-start=\"110\" data-end=\"313\">In <strong data-start=\"113\" data-end=\"164\"><a href=\"https:\/\/mxs-refractories.com\/glossary-refractories\/silica-refractories-definition\/\">silica refractory bricks<\/a> used in glass furnaces<\/strong>, controlling the amount of <strong data-start=\"192\" data-end=\"211\">residual quartz<\/strong> is critical. This is why technical specifications generally require <strong data-start=\"280\" data-end=\"312\">less than 1% residual quartz<\/strong>.<\/p>\n<h3 data-section-id=\"hhnneg\" data-start=\"315\" data-end=\"384\">1. A phase transformation that generates dangerous volume changes<\/h3>\n<p data-start=\"386\" data-end=\"477\">Quartz undergoes a crystallographic transformation <strong data-start=\"437\" data-end=\"476\">from \u03b1-quartz to \u03b2-quartz at 573 \u00b0C<\/strong>.<\/p>\n<p data-start=\"479\" data-end=\"543\">This transformation produces a <strong data-start=\"510\" data-end=\"542\">sudden volume change (\u22480.8%)<\/strong>.<\/p>\n<p data-start=\"545\" data-end=\"603\">In a brick already installed in a glass furnace, this can:<\/p>\n<ul data-start=\"605\" data-end=\"745\">\n<li data-section-id=\"1a1fp5b\" data-start=\"605\" data-end=\"649\">\n<p data-start=\"607\" data-end=\"649\">generate <strong data-start=\"616\" data-end=\"649\">significant internal stresses<\/strong><\/p>\n<\/li>\n<li data-section-id=\"2jf6io\" data-start=\"650\" data-end=\"696\">\n<p data-start=\"652\" data-end=\"696\">cause <strong data-start=\"658\" data-end=\"696\">microcracks or structural cracking<\/strong><\/p>\n<\/li>\n<li data-section-id=\"1ewqco4\" data-start=\"697\" data-end=\"745\">\n<p data-start=\"699\" data-end=\"745\">disturb the <strong data-start=\"711\" data-end=\"745\">stability of the furnace crown<\/strong><\/p>\n<\/li>\n<\/ul>\n<p data-start=\"747\" data-end=\"864\">In glass furnaces, where <strong data-start=\"772\" data-end=\"810\">dimensional stability is essential<\/strong>, this phenomenon can become a major operational risk.<\/p>\n<h3 data-section-id=\"dj2x68\" data-start=\"866\" data-end=\"926\">2. Bricks must already be stabilized before installation<\/h3>\n<p data-start=\"928\" data-end=\"993\">During manufacturing, firing must convert almost all quartz into:<\/p>\n<ul data-start=\"995\" data-end=\"1029\">\n<li data-section-id=\"kj48z3\" data-start=\"995\" data-end=\"1010\">\n<p data-start=\"997\" data-end=\"1010\"><a href=\"https:\/\/en.wikipedia.org\/wiki\/Tridymite\" target=\"_blank\" rel=\"noopener\"><strong data-start=\"997\" data-end=\"1010\">tridymite<\/strong><\/a><\/p>\n<\/li>\n<li data-section-id=\"b8lyun\" data-start=\"1011\" data-end=\"1029\">\n<p data-start=\"1013\" data-end=\"1029\"><a href=\"https:\/\/fr.wikipedia.org\/wiki\/Cristobalite\" target=\"_blank\" rel=\"noopener\"><strong data-start=\"1013\" data-end=\"1029\">cristobalite<\/strong><\/a><\/p>\n<\/li>\n<\/ul>\n<p data-start=\"1031\" data-end=\"1159\">These phases are <strong data-start=\"1048\" data-end=\"1076\">thermodynamically stable<\/strong> in the operating temperature range of glass furnaces (typically <strong data-start=\"1141\" data-end=\"1157\">1400\u20131650 \u00b0C<\/strong>).<\/p>\n<p data-start=\"1161\" data-end=\"1269\">If a significant amount of quartz remains, it means that <strong data-start=\"1218\" data-end=\"1268\">the mineralogical transformation is incomplete<\/strong>.<\/p>\n<p data-start=\"1271\" data-end=\"1381\">As a result, phase transformation may still occur <strong data-start=\"1321\" data-end=\"1349\">during furnace operation<\/strong>, which is clearly unacceptable.<\/p>\n<h3 data-section-id=\"1dwr1w4\" data-start=\"1383\" data-end=\"1424\">3. A risk factor for furnace lifetime<\/h3>\n<p data-start=\"1426\" data-end=\"1452\">In critical areas such as:<\/p>\n<ul data-start=\"1454\" data-end=\"1524\">\n<li data-section-id=\"u289me\" data-start=\"1454\" data-end=\"1469\">\n<p data-start=\"1456\" data-end=\"1469\">the <strong data-start=\"1460\" data-end=\"1469\">crown<\/strong><\/p>\n<\/li>\n<li data-section-id=\"otxyyt\" data-start=\"1470\" data-end=\"1494\">\n<p data-start=\"1472\" data-end=\"1494\">the <strong data-start=\"1476\" data-end=\"1494\">superstructure<\/strong><\/p>\n<\/li>\n<li data-section-id=\"qm8zry\" data-start=\"1495\" data-end=\"1524\">\n<p data-start=\"1497\" data-end=\"1524\">the <strong data-start=\"1501\" data-end=\"1524\">upper furnace walls<\/strong><\/p>\n<\/li>\n<\/ul>\n<p data-start=\"1526\" data-end=\"1563\">mechanical stresses are already high.<\/p>\n<p data-start=\"1565\" data-end=\"1600\">Excess residual quartz may lead to:<\/p>\n<ul data-start=\"1602\" data-end=\"1675\">\n<li data-section-id=\"d6q02t\" data-start=\"1602\" data-end=\"1625\">\n<p data-start=\"1604\" data-end=\"1625\"><strong data-start=\"1604\" data-end=\"1625\">crown deformation<\/strong><\/p>\n<\/li>\n<li data-section-id=\"r04stm\" data-start=\"1626\" data-end=\"1645\">\n<p data-start=\"1628\" data-end=\"1645\"><strong data-start=\"1628\" data-end=\"1645\">joint opening<\/strong><\/p>\n<\/li>\n<li data-section-id=\"1x64yjt\" data-start=\"1646\" data-end=\"1675\">\n<p data-start=\"1648\" data-end=\"1675\"><strong data-start=\"1648\" data-end=\"1675\">weakening of the bricks<\/strong><\/p>\n<\/li>\n<\/ul>\n<p data-start=\"1677\" data-end=\"1756\">Ultimately, this can significantly <strong data-start=\"1712\" data-end=\"1755\">reduce the campaign life of the furnace<\/strong>.<\/p>\n<h3 data-section-id=\"3sgy4w\" data-start=\"1758\" data-end=\"1797\">4. Why the industry standard is &lt;1%<\/h3>\n<p data-start=\"1799\" data-end=\"1865\">Refractory manufacturers have established through experience that:<\/p>\n<ul data-start=\"1867\" data-end=\"2093\">\n<li data-section-id=\"1im4h1i\" data-start=\"1867\" data-end=\"1952\">\n<p data-start=\"1869\" data-end=\"1952\"><strong data-start=\"1869\" data-end=\"1892\">&lt;1% residual quartz<\/strong> ensures that critical transformations have already occurred<\/p>\n<\/li>\n<li data-section-id=\"cou4w1\" data-start=\"1953\" data-end=\"2020\">\n<p data-start=\"1955\" data-end=\"2020\">the microstructure is dominated by <strong data-start=\"1990\" data-end=\"2020\">tridymite and cristobalite<\/strong><\/p>\n<\/li>\n<li data-section-id=\"1ddi2ie\" data-start=\"2021\" data-end=\"2093\">\n<p data-start=\"2023\" data-end=\"2093\">the refractory exhibits <strong data-start=\"2047\" data-end=\"2093\">excellent dimensional stability in service<\/strong><\/p>\n<\/li>\n<\/ul>\n<p data-start=\"2095\" data-end=\"2222\">For this reason, <strong data-start=\"2112\" data-end=\"2221\">&lt;1% residual quartz has become an industry benchmark for silica bricks used in glass furnace applications<\/strong>.<\/p>\n<p data-start=\"2229\" data-end=\"2245\"><strong data-start=\"2231\" data-end=\"2245\">In summary<\/strong><\/p>\n<p data-start=\"2247\" data-end=\"2300\">Maintaining <strong data-start=\"2259\" data-end=\"2291\">less than 1% residual quartz<\/strong> ensures:<\/p>\n<ul data-start=\"2302\" data-end=\"2459\" data-is-last-node=\"\" data-is-only-node=\"\">\n<li data-section-id=\"141ur1e\" data-start=\"2302\" data-end=\"2344\">\n<p data-start=\"2304\" data-end=\"2344\">no dangerous volume change at <strong data-start=\"2334\" data-end=\"2344\">573 \u00b0C<\/strong><\/p>\n<\/li>\n<li data-section-id=\"bx7pa6\" data-start=\"2345\" data-end=\"2377\">\n<p data-start=\"2347\" data-end=\"2377\"><strong data-start=\"2347\" data-end=\"2377\">high dimensional stability<\/strong><\/p>\n<\/li>\n<li data-section-id=\"136mb4w\" data-start=\"2378\" data-end=\"2422\">\n<p data-start=\"2380\" data-end=\"2422\"><strong data-start=\"2380\" data-end=\"2422\">mechanical safety of the furnace crown<\/strong><\/p>\n<\/li>\n<li data-section-id=\"1y7ogpq\" data-start=\"2423\" data-end=\"2459\" data-is-last-node=\"\">\n<p data-start=\"2425\" data-end=\"2459\" data-is-last-node=\"\"><strong data-start=\"2425\" data-end=\"2458\">maximum furnace campaign life<\/strong>.<\/p>\n<\/li>\n<\/ul>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"z-0 flex min-h-[46px] justify-start\"><\/div>\n<div class=\"mt-3 w-full empty:hidden\">\n<div class=\"text-center\"><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/article>\n<\/div>\n<div class=\"pointer-events-none h-px w-px absolute bottom-0\" aria-hidden=\"true\" data-edge=\"true\"><\/div>\n<\/div>\n<div id=\"thread-bottom-container\" class=\"sticky bottom-0 group\/thread-bottom-container relative isolate z-10 w-full basis-auto 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text-xs [view-transition-name:var(--vt-disclaimer)] md:px-[60px]\"><\/div>\n<\/div>\n<\/div>\n<\/div>\n<p>&nbsp;<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<div><\/div>\n<\/div>\n<\/div>\n<p><audio class=\"fixed start-0 bottom-0 hidden h-0 w-0\" crossorigin=\"anonymous\" autoplay=\"autoplay\" data-mce-fragment=\"1\"><\/audio><!--$--><!--$--><!--$--><!--\/$--><!--\/$--><!--\/$--> <span id=\"PING_CONTENT_DLS_POPUP\"><\/span><\/p>\n<div><\/div>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; In silica refractory bricks used in glass furnaces, controlling the amount of residual quartz is critical. This is why technical specifications generally require less than 1% residual quartz. 1. A phase transformation that generates dangerous volume changes Quartz undergoes a crystallographic transformation from \u03b1-quartz to \u03b2-quartz at 573 \u00b0C. This transformation produces a sudden [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":555,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_post_was_ever_published":false},"categories":[20],"tags":[],"class_list":["post-554","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-materials-properties"],"jetpack_featured_media_url":"https:\/\/mxs-refractories.com\/wp-content\/uploads\/2026\/03\/ChatGPT-Image-11-mars-2026-14_51_38.png","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/posts\/554","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/comments?post=554"}],"version-history":[{"count":3,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/posts\/554\/revisions"}],"predecessor-version":[{"id":558,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/posts\/554\/revisions\/558"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/media\/555"}],"wp:attachment":[{"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/media?parent=554"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/categories?post=554"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/mxs-refractories.com\/de\/wp-json\/wp\/v2\/tags?post=554"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}